Publications

By Year

  1. Y. Chen, H. Chen, A. Aleksandrov, and T. M. Orlando. 2008. The Roles of Water, Acidity and Surface Morphology on Surface Assisted Laser Desorption. J Phys Chem C, (accepted).
  2. T. M. Orlando, D. Oh, and Y. Chen. 2008. The Role of Diffraction and Compound Feshbach Resonances in Low-energy Electron Induced Damage of Hydrated DNA. J Chem Phys, (accepted).
  3. G. A. Grieves, N. Petrik, J. Herring-Captain, B. Olanrewaju, A. Aleksandrov, R. G. Tonkyn, S. A. Barlow, G. A. Kimmel, and T. M. Orlando. 2008. Photoionization of Sodium Salt Solutions in a Liquid Jet. J Phys Chem C, (accepted).
  4. H. Chen, A. Alexandrov, M. Lui, and T. M. Orlando. 2008. Oxygen Adsorption Intermediates on Gd-doped Ceria Surfaces Investigated by Electron Stimulated Desorption Appl Surf Sci (in press).
  5. C. D. Lane, N. G. Petrik, T. M. Orlando, G. A. Kimmel. 2007. Site-Dependent Electron-Stimulated Reactions in Water Films on TiO2(110). J Chem Phys, 127(22), 224706/1-224706/9.
  6. C. D. Lane, N. G. Petrik, T. M. Orlando, G. A. Kimmel. 2007. Electron-Stimulated Oxidation of Thin Water Films Adsorbed on TiO2(110). J Phys Chem C, 111, 16319-16329.
  7. C. D. Lane, T. M. Orlando. 2007. Inelastic Electron Scattering and Energy-selective Negative Ion Reactions on Silicon Surfaces and Interfaces. Appl Surf Sci, 253(16), 6646-6656.
  8. Y. Chen, C. M. Sullards, T. T. Hoang, S. W. May, T. M. Orlando. 2006. Analysis of Organoselenium and Organic Acid Metabolites by Laser Desorption Single Photon Ionization Mass Spectrometry. Anal Chem, 78(24), 8386-8394.
  9. D. Oh, M. T. Sieger, T. M. Orlando. 2006. Zone Specificity in the Low-energy Electron Stimulated Desorption of Cl+ from Reconstructed Si(111)-7×7 surfaces. Surf Sci, 600(19), L245-L249.
  10. H. Chen, A. Aleksandrov, S. Zha, M. Liu, T. M. Orlando. 2006. Highly Efficient Electron Stimulated Desorption of O+ from Gadolinia-Doped Ceria Surfaces. J Phys Chem B, 110, 10779-10784.
  11. C. D. Lane, T. M. Orlando. 2006. Low-energy Electron Stimulated Desorption of Neutrals from SiCl4 Mulitlayers Adsorbed on Si(111). J Chem Phys 124, 164702
  12. J. Summerour, Y. Chen, M. Josowicz, T. M. Orlando, J. Janata, A. Paulenova. 2006. A Beta Microirradiator. Radiat Phys Chem, 75, 369.
  13. R. E. Johnson, P. D. Cooper, T. I. Quickenden, G. A. Grieves, T. M. Orlando. 2005. Production of Oxygen by Electronically-induced Dissociations in Ice. J Chem Phys, 123, 184715-1.
  14. C. D. Lane, K. R. Shpperd,A. B. Aleksandrov,T. M. Orlando. 2005. Electron Stimulated Desorption of Cations from SiCl4 Multilayers Adsorbed on Si(111). Surf Sci 593, 173.
  15. G. A. Grieves, T. M. Orlando. 2005. The Importance of Pores in the Electron Stimulated Production of H2 and O2 in Low Temperature Ice. Surf Sci, 593, 180.
  16. T.M. Orlando, T.B. McCord and G.A. Grieves. 2005. The Chemical Nature of Europa Surface Material and the Relation to a Sub-surface Ocean. Icarus 177, 528.
  17. J. Herring-Captain, G. A. Grieves, A. Alexandrov, M. T. Sieger, H. Chen, T. M. Orlando. 2005. Low-energy (5-250 eV) Electron Stimulated Desorption of H+, H2+ and H+(H2O)n from Low-temperature Water Ice Surfaces. Phys Rev B: Condens Matter, 72, 035431.
  18. H. Chen, A. Alexandrov, Y. Chen, S. Zhua, M. Liu and T. M. Orlando. 2005. Probing Water Interactions and Vacancy Production on Gadolinia-doped Ceria Surfaces using Electron-Stimulated Desorption. J Phys Chem B, 109, 11257-62.
  19. B. C. Garrett, et. al. including T. M. Orlando. 2005. Role of Water in Electron-initiated Processes and Radical Chemistry: Issues and Scientific Advances. Chem Rev, 105, 355.
  20. H. Chen, Y. Chen, A. Aleksandrov, J. Dong, M. Liu, T. M. Orlando. 2005. Charging Effects on Electron-stimulated Desorption of Cations from Gadolinia-doped Ceria Surfaces. Appl Surf Sci, 243, 166-177.
  21. J. Herring, A. Aleksandrov, T. M. Orlando. 2004. The Stimulated Desorption of Cations from Pristine and Acidic Low-temperature Ice Surfaces. Phys Rev Lett 92, 187602-1.
  22. T. M. Orlando, D. Oh, M. T. Sieger and C. D. Lane. 2004. Electron Collisions with Complex Targets: Diffraction Effects in Stimulated Desorption. Physica Scripta, T110, 256.
  23. T. M. Orlando, A. Alexandrov, A. Lebsack, J. Herring, and J. Hoard. 2004. The reactions of NO2 and CH3CHO with Na-Y Zeolites and the Relevance to Plasma Activated Lean NOx Catalysis. Catalysis Today, 89, 151.
  24. T. M. Orlando, L. Merhari, D. P. Taylor and K. Ikuta, Editors. 2003. Three-Dimensional Nanoengineered Assemblies. Materials Research Society Proceedings, Volume 739
  25. T. M. Orlando, A. B. Aleksandrov, J. Herring. 2003. Electron-Stimulated Desorption of H+, H2+, OH+, and H+(H2O) from Water-Covered Zirconia Surfaces. J Phys Chem B 107, 9370.
  26. L. Siller, M. T. Sieger, T. M. Orlando. 2003. Electron-stimulated Reactions Involving D2O Co-adsorbed with CO2 Ice at VUV/EUV Energies. J Chem Phys 118, 8898.
  27. T. M. Orlando, M. T. Sieger. 2003. The Role of Electron-Stimulated Production of O2 from Water Ice in the Radiation Processing of Outer Solar System Surfaces. Surf Sci 528, 1.
  28. T. B. McCord, G. Teeter, G. B. Hansen, M. T. Sieger, T. M. Orlando. 2002. Brines Exposed to Europa Surface Conditions. J Geophys Res, [Planets] 107, 4-1.
  29. T. E. Madey, R. E. Johnson, T. M. Orlando. 2002. Far-out Surface Science: Radiation-Induced Surface Processes in the Solar System. Surf Sci 500, 838.
  30. T. B. McCord, T. M. Orlando, G. Teeter, G. B. Hansen, M. T. Sieger, N. G. Petrik, L. Van Keulen. 2001. Thermal and Radiation Stability of the Hydrated Salt Minerals Epsomite, Mirabilite and Natron Under Europa Environmental Conditions. J Geophys Res, [Planets] 106, 3311.
  31. A. Alexandrov, M. Piacentini, N. Zema, A. C. Felici, T. M. Orlando. 2001. The Role of Surface Excitons of Stimulated Desorption of KI(100). Phys Rev Lett 86, 536.
  32. V. Shutthanandan, S. Thevuthasan, J. S. Young, T. M. Orlando, W. J. Weber. 2001. Hydrogen Damage Interactions in Yttria-Stabilized Zirconia. J Nucl Mater 289, 128.
  33. D. Meisel, D. Camaioni, and T. M. Orlando. 2001. Radiation Chemistry and Nuclear Waste: The NOx System and Organic Aging, ACS Symposium Series 778. Nulcear Site Remediation, First Accomplishments of the Environmental Management Science Program Ed. W. Heineman and G. Eller Chapter 21, pgs. 342-363.
  34. T. M. Orlando and D. Mesiel. 2001. Radiation-Induced Processes in Aqueous Suspensions of Nanoparticles and Nanoscale Water Films:Relevance to H2 Production in Mixed Waste and Spent Nuclear Fuel, ACS Symposium Series 778. Nulcear Site Remediation, First Accomplishments of the Environmental Management Science Program Ed. W. Heineman and G. Eller Chapter 17, pgs. 284-298.
  35. M. T. Sieger, T. M. Orlando. 2000. Incident Beam Diffraction in Electron Stimulated Desorption. Surf Sci 451, 31.
  36. A. Alexandrov, M. Piacentini, R. G. Tonkyn, M. T. Sieger, N. Zema, T. M. Orlando. 2000. Electron-Stimulated Desorption of I from KI(100): An Energy and Temperature Dependent Study. Surf Sci 451, 208.
  37. T. B. McCord, G. Teeter, G. B. Hansen, M. T. Sieger, T. M. Orlando. 2000. Frozen Brines on Europa's Surface. Bull Astron Soc 32, 1068.
  38. M. T. Sieger, T. M. Orlando. 2000. Probing Low-Temperature Water Ice Phases Using Electron-Stimulated Desorption. Surf Sci 451, 97.
  39. N. G. Petrik, K. Knutsen, E. Paparazzo, S. Lea, D. M. Camaioni, T. M. Orlando. 2000. Electron-Beam Induced Damage of NaNO3 Single Crystals. J Phys Chem B 104, 1563.
  40. T. B. McCord, G. B. Hansen, D. Matson, T. M. Orlando, M. T. Sieger, N. G. Petrik, L. Van Keulen, J. K. Crowley. 2000. Behavior of Hydrated Sulfates and Carbonates under Europa’s Surface Conditions. Lunar Planet Sci. [CD-ROM] XXXI Lunar and Planetary Institute, Houston, TX, (1999) abstract 1541.
  41. T. B. McCord, G. B. Hansen, T. M. Orlando, M. T. Sieger, G. Teeter, N. G. Petrik, L. Van Keulen, J. K. Crowley. 1999. Hydrated Sulfates and Carbonates and their Stability on Europa's Surface (abstract). EOS Tran AGU 80 (46), Fall Meet Suppl. F599.
  42. T. B. McCord, F. P. Fanale, G. B. Hansen, T. M. Orlando, M. T. Sieger, N. G. Petrik, J. Crowley. 1999. On Hydrated Sulfates and Carbonates on Europa's Surface (abstract). Bull Am Astron Soc 31, 1171.
  43. N. G. Petrik, A. Alexandrov, T. M. Orlando, A. I. Hall. 1999. Radiation-Induced Processes at Oxide Interfaces Relevant to Spent Nuclear Fuel Storage. American Nuclear Society Transactions 81, 101.
  44. T. B. McCord, G. B. Hansen, T. M. Orlando, M. Sieger, J. K. Crowley, C. A. Hibbitts, L. Van Keulen. 1999. Properties of Hydrated Salts Including Under Europa Conditions. Lunar and Planetary Science XXX Lunar and Planetary Institute, Houston, TX.
  45. T. M. Orlando, M. T. Sieger, W. C. Simpson. 1999. Laboratory Studies of the Production of O2 on Icy Satellites by Electronic Excitation. Lunar and Planetary Science XXX Lunar and Planetary Institute, Houston, TX.
  46. T. M. Orlando, G. A. Kimmel, W. C. Simpson. 1999. Quantum-Resolved Electron Stimulated Interface Reactions: D2 Formation from D2O Films. Nucl Instrum Methods Phys Res, Sect B 157, 183.
  47. N. Petrik, D. P. Taylor, T. M. Orlando. 1999. Laser-Stimulated Luminescence of ZrO2(100) and (110) Single Crystals: Carrier Recombination Kinetics and Defects States. J of Appl Physics 85, 6770.
  48. M. T. Sieger, G. K. Schenter, T. M. Orlando. 1999. Stimulated Desorption by Surface Electron Standing Waves. Phys Rev Lett 82, 3348.
  49. W. C. Simpson, W. K. Wang, J. A. Yarmoff, T. M. Orlando. 1999. Electron- and Photon-Stimulated Desorption of O+ from Zirconia. Surf Sci 423, 225.
  50. M.L. Balmer, R. Tonkyn, A.Y. Kim, J. Hoard, I. S. Yoon, D. Jimenez, T. M. Orlando, S. Barlow. 1998. Nitrogen Measurement from NOx Reduction for a Plasma-Catalyst System in Simulated Diesel Exhaust. Proceedings of the 1998 Diesel Engine Emissions Reduction Workshop.
  51. M. L. Balmer, R. G. Tonkyn, A. Kim, S. Yoon, D. Jimenez, T. M. Orlando, S. E. Barlow, J. Hoard. 1998. Diesel NOx Reduction on Surfaces in Plasma. Society of Automobile Engineers Proceedings on Emissions Control.
  52. M. T. Sieger, W. C. Simpson, T. M. Orlando. 1998. Production of O2 on Icy Satellites by Electronic Excitation of Low-Temperature Water Ice. Nature 394, 554.
  53. D. P. Taylor, W. C. Simpson, K. Knutsen, M. A. Henderson, T. M. Orlando. 1998. Photon-Stimulated Desorption and Laser Ablation of Ytrria-Stabilized ZrO2(100) Crystals. Appl Surf Sci 127-129, 101.
  54. K. Knutsen, T. M. Orlando. 1998. Low-Energy (5-100 eV) Electron- and Ultraviolet (6.4 eV) Photon-Stimulated Desorption of Neutral Fragments from NaNO3 Single Crystals. Appl Surf Sci 127-129, 1.
  55. W. C. Simpson, T. M. Orlando, L. Parenteau, K. Nagesha, L. Sanche. 1998. Dissociative Electron Attachment in Nanoscale Ice Films: Thickness and Charging Effects. J Chem Phys 108, 5027.
  56. D. Meisel, A. Cook, D. Camaioni, T. M. Orlando. 1997. Chemistry, Radiation and Interfaces in Suspensions of Nuclear Waste Simulants. Photoelectrochemistry Ed. K. Rajeshwar, L. M. Peter, A. Fujishima, D. Meisner, M. Tomkiewicz, The Electrochemical Society Pub. Vol. 97-20, 350.
  57. R. G. Tonkyn, M. L. Balmer, S. E. Barlow, T. M. Orlando, D. Goulette. 1997. Vehicle Exhaust Treatment Using Electrical Discharge and Materials Chemistry. Proc. of 1997 Diesel Exhaust Reductions Workshop 115 - 122.
  58. W. C. Simpson, M. T. Sieger, T. M. Orlando, L. Parenteau, K. Nagesha, L. Sanche. 1997. Dissociative Electron Attachment in Nanoscale Ice Films: Temperature and Morphology Effects. J Chem Phys 107, 8668.
  59. W. C. Simpson, L. Parenteau, R. S. Smith, L. Sanche, T. M. Orlando. 1997. Electron-Stimulated Desorption of D- (H-) from condensed D2O (H2O) films. Surf Sci 390, 79.
  60. W. C. Simpson, M. T. Sieger, G. A. Kimmel, L. Perenteau, L. Sanche, T. M. Orlando. 1997. Dissociative Electron Attachment Resonances in Nanoscale Ice Films. Radiat Res 148, 491.
  61. T. M. Orlando, G. A. Kimmel. 1997. The Role of Excitons and Substrate Temperature in the Low-Energy (5-50 eV) Electron-Stimulated Dissociation of Amorphous D2O Ice. Surf Sci 390, 86.
  62. M. T. Sieger, T. M. Orlando. 1997. Effect of Surface Roughness on the Electron-Stimulated Desorption of D+ from Micro-porous D2O Ice. Surf Sci 390, 92.
  63. M. T. Sieger, W. C. Simpson, T. M. Orlando. 1997. The Electron-Stimulated Desorption of D+ from D2O Ice: Surface Structure and Electronic Excitations. Phys Rev B: Condens Matter 56, 4925.
  64. K. Knutsen, T. M. Orlando. 1997. Photon-Stimulated Desorption of O (3PJ) and NO (2Π) from NaNO3 Single Crystals. Phys Rev B: Condens Matter 55, 13246.
  65. G. A. Kimmel, T. M. Orlando, P. Cloutier, L. Sanche. 1997. Low-Energy (5-50 eV) Electron-Stimulated Desorption of Atomic Hydrogen and Metastable Emission from Amorphous Ice. J Phys Chem B 101, 6301.
  66. R. G. Tonkyn, M. Balmer, S. Barlow, T. M. Orlando, D. Goulette. 1997. Vehicle Exhaust Treatment Using Electrical Discharge Methods. Society of Automobile Engineers Proceedings on Emissions Control Paper 971716.
  67. G. A. Kimmel, T. M. Orlando. 1996. Observation of Negative Ion Resonances in Amorphous Ice via Low-Energy Electron-Stimulated Production of Molecular Hydrogen. Phys Rev Lett 77, 3983.
  68. K. Knutsen, Y. Su, K. Keefer, T. M. Orlando. 1996. Mechanisms of Radiolytic Decomposition of Complex Nuclear Waste Forms. Proc Am Nucl Soc Progress in Hazardous Waste Cleanup Vol. 1, pg. 616 - 619
  69. R. G. Tonkyn, S. E. Barlow, T. M. Orlando. 1996. Decomposition of Carbon Tetrachloride Using a Packed-Bed Corona Reactor. J of Appl Physics 80, 4877
  70. O. Kornienko, S. Brynjelsen, L. Hanley, T. M. Orlando. 1996. Analysis of EDTA Samples via Laser Desorption in a Quadrupole Ion Trap. Proc 42nd ASMS Conf Mass Spectrom Allied Topics
  71. M. C. Hsiao, B. T. Merritt, B. M. Penetrante, G. E. Vogtlin, P. H. Wallman, R. G. Tonkyn, R. Shah, T. M. Orlando. 1996. Plasma Assisted Oxidation of Propene. J of Adv Oxid Tech 1, 79.
  72. K. Knutsen, T. M. Orlando. 1996. Low-Energy (5-80 eV) Electron-Stimulated Desorption of H+(D+), OH+ (OD+), O+, and NO+ from Solution Grown NaNO3 Crystals. Surf Sci 348, 143.
  73. B. Lerner, J. Birmingham, R. G. Tonkyn, S. E. Barlow, T. M. Orlando. 1995. Decomposition of Trichloroethylene by a Large Scale, High Flow Packed-Bed Gas-Phase Corona Reactor. Proceedings of 12th Int Symp on Plasma Chemistry.
  74. G. A. Kimmel, R. G. Tonkyn, T. M. Orlando. 1995. Kinetic and Internal Energy Distributions of Molecular Hydrogen Produced from Amorphous Ice by Impact of 100 eV Electrons. Nucl Instrum Methods Phys Res, Sect B 101, 179.
  75. G. A. Kimmel, T. M. Orlando. 1995. Low-Energy (5-120 eV) Electron-Stimulated Dissociation of Amorphous D2O Ice: D(2S), O(3P2,1,0), and O(1D2) Yields and Velocity Distributions. Phys Rev Lett 75, 2606.
  76. R. A. Bradley, Jr., E. J. Lanzendorf, M. I. McCarthy, T. M. Orlando, W. P. Hess. 1995. "Laser Interactions with an Ionic Molecular Crystal: Sodium Nitrate Ablation in the 6 eV Valence Band. J Phys Chem 99, 11715.
  77. A. Perrung, J. P. Cowin, S. E. Barlow, G. Teeter, T. M. Orlando. 1995. Space-Charge Induced Acceleration of Ions Emitted by Laser-Irradiated Surfaces. J of Appl Physics 78, 481.
  78. G. A. Kimmel, T. M. Orlando, C. Vezina, L. Sanche. 1994. "Low-Energy (5-50 eV) Electron-Stimulated Production of Molecular Hydrogen from Amorphous Water Ice. J Chem Phys 101, 3282.
  79. T. M. Orlando, J. P. Cowin, G. Teeter, S. E. Barlow. 1994. Dynamical Acceleration Effects in Laser-Induced Particle Emission from Surfaces, pgs. 341-346 Lecture Notes in Physics, Laser Ablation Mechanisms, and Applications edited by J. C. Miller and R. Haglund, Jr. (Springer-Verlag, New York).
  80. T. M. Orlando, A. R. Burns, E. B. Stechel, D. R. Jennison. 1993. Quantum-Resolved Stimulated Surface Reactions. Desorption Induced by Electronic Transitions, DIET V edited by A. R. Burns, E. B. Stechel, and D. R. Jennison (Springer-Verlag, New York), 194.
  81. T. M. Orlando, A. R. Burns, D. R. Jennison, E. B. Stechel. 1992. Electronically Stimulated Adsorbate Dissociation in the Presence of an Electronegative Coadsorbate: (NO2 + O) on Pt(111). Phys Rev B: Condens Matter 45, 8679.
  82. A. R. Burns, E. B. Stechel, D. R. Jennison, T. M. Orlando. 1992. Effects of Coadsorbed Atomic Oxygen on the Electron-Stimulated Desorption of Neutral NO from Pt(111). Phys Rev B: Condens Matter 45, 1373.
  83. T. M. Orlando, A. R. Burns, E. B. Stechel, D. R. Jennison. 1991. Resonance Ionization Detection of Neutral O (3PJ) Produced from Stimulated Surface Processes. J Vac Sci and Tech A9, 1769.
  84. A. R. Burns, T. M. Orlando, D. R. Jennison, E. B. Stechel. 1991. State-Resolved Study of Coadsorption Effects on the Stimulated Dissociation of NO2 on Pt(111). J Vac Sci and Tech A9, 1774.
  85. T. M. Orlando, A. R. Burns, E. B. Stechel, D. R. Jennison. 1991. Quantum Resolved Studies of Electron-Stimulated Reactions on Adsorbate Covered Pt(111) Surfaces. Nucl Instrum Methods Phys Res, Sect B 58, 477.
  86. T. M. Orlando, A. R. Burns, E. B. Stechel, D. R. Jennison. 1990. Electron-stimulated production of NO2(g) from O2 coadsorbed with NO on Pt(111). J Chem Phys 93(12):9197.
  87. T. M. Orlando, A. Friedmann, J. P. Maier. 1990. Photodissociation Spectroscopy of the (OCS:C2H2)+ Cluster Ion. J Chem Phys 92, 7365.
  88. T. M. Orlando, B. Yang, Y. Chiu, S. L. Anderson. 1990. The Effects of Different Vibrational Modes and Collision Energy on the Reaction of Acetylene Cations with Carbonyl Sulfide. J Chem Phys 92, 7356.
  89. B. Yang, T. M. Orlando, Y. Chiu, S. L. Anderson. 1989. Vibrational Mode Effects on Ion-Molecule Reactions. XVI ICPEAC Proceedings, NY.
  90. T. M. Orlando, B. Yang, S. L. Anderson. 1989. The Effects of Bending and Stretching Vibration on the Reaction of Acetylene Cations with Methane. J Chem Phys 90, 1577.
  91. T. M. Orlando, S. L. Anderson, J. R. Appling, M. G. White. 1987. Multiphoton Ionization Photoelectron Spectroscopy of Ungerade Excited States of Acetylene: Intermediate State Mixing and Ion-State Selection. J Chem Phys 87, 852.
  92. J. R. Appling, M. G. White, T. M. Orlando, S. L. Anderson. 1986. Observation of Circular Dichroism in Photoelectron Angular Distributions. J Chem Phys 85, 6803.
  93. T. M. Orlando, L. Li, S. L. Anderson, M. G. White. 1986. Third Harmonic Interference Effects in the MPI Spectrum of Acetylene. Chem. Phys. Lett 129, 31.
  94. J. S. Gaffney, E. T. Premuzic, T. Orlando, S. Ellis, P. Snyder. 1983. Gas Chromatography-Circular Dichroism System for Detection of Optically Active Substances. J of Chrom 262, 321.